In-situ formation of the adsorbent based on octadecylamine for the extraction of Ag+ ions from aqueous solutions and its determination by microinjection flame atomic absorption spectrometry.

Abstract

In this research, a dispersive solid phase extraction procedure based on changing the solubility of octadecylamine with pH was proposed to determine Ag+ ions in different water samples. For this purpose, first, the pH of sample solution containing the analyte was adjusted to 10.5. Then desired volume of the octadecylamine dissolved in acidic solution was injected into the solution. Because of the low solubility of octadecylamine in alkaline solution, a cloudy state was formed. The produced octadecylamine particles acted as a complexing agent for Ag+ ions and adsorbent for the formed complex. The obtained cloudy solution was centrifuged and the sedimented particles were removed and dissolved in a diluted nitric acid solution. It was injected into a flame atomic absorption spectrometry to determine the extracted amounts of the analyte. The effect of important parameters such as the amount of octadecylamine, volume of nitric acid, and centrifugation and vortexing conditions on the extraction efficiency of the procedure was studied and optimized. In optimal conditions, the developed method showed a linear range of 0.50-200 µg L-1. The limits of detection and quantification were 0.18 and 0.50 µg L-1, respectively. Extraction recovery was 93.6%. The relative standard deviations were less than 4%. The effectiveness of the method was investigated by determination of Ag+ ions in water and wastewater samples.