Abstract
The first in situ Fe K-edge X-ray absorption fine structure study is reported on the electronic and structural properties of a nitrosyl [meso-tetrakis(p-methoxyphenyl) porphyrinato]iron(II) adduct, [Fe(NO)(TMPP)], adsorbed onto a high-area carbon electrode. This adsorbed complex displayed a remarkable stability over a wide potential range, and multiple-scattering XAFS analysis yielded bond lengths of Fe−Np = 1.99, Fe−NNO = 1.74, and Fe−OH2 = 2.02 Å, and an Fe−N−O bond angle of 155°, characteristic of FeIINO porphyrin adducts.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
