In situ fabrication of a plasmonic Bi@Bi2O2CO3 core-shell heterostructure for photocatalytic CO2 reduction: structural insights into selectivity modulation.

Abstract

The precise design of active sites and light absorbers is essential for developing highly efficient photocatalysts for CO2 reduction. Core-shell heterostructures constructed based on large-sized plasmonic Bi metals are ideal candidates because of the utilization of full-spectrum light and effective charge separation. However, the mechanism of selectivity modulation of large-sized Bi@semiconductor photocatalysts has yet to be explored in depth. Herein, a plasmonic Bi@Bi2O2CO3 core-shell heterostructure was successfully synthesized via a facile solvothermal treatment in deep eutectic solvents, demonstrating highly efficient photocatalytic CO2 reduction. This structure features a sizeable Bi sphere with a thin, epitaxially grown Bi2O2CO3 shell, which allows for the utilization of the entire light spectrum. Additionally, the oxygen vacancies in the Bi2O2CO3 shell can rapidly trap electrons transferred from the Bi core via Bi-O-Bi bonds, thereby forming abundant electron-rich interfaces that serve as the active sites for activating reactant molecules and facilitating the reaction.