Abstract
AbstractElectron spin resonance (ESR) spectroscopy was used to study the anchoring of a Au complex and gold nanoparticles in NaY type zeolites. The complex of Au(II) with two nitrogen atoms of two ethylenediamine ligands [giso = 2.053, A (Au) = 16.4 G, A (N) = 15.0 G.] in the supercage of the zeolite and conduction electron spin resonance (CESR) of gold particles with 1.56‐nm diameter (g = 2.064) were observed. Their formation and stability were related with the gold concentration and the pre‐treatment conditions. The small gold particles stabilized in the supercage of zeolite were formed in the samples with low gold concentration after oxygen pre‐treatment. The confinement in the zeolite pores obviously prevents the Au(II) complex bound to two nitrogen ligands from undergoing disproportionation. Copyright © 2009 Curtin University of Technology and John Wiley & Sons, Ltd.
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