In Situ Embedded Pseudo Pd-Sn Solid Solution in Micropores Silica with Remarkable Catalytic Performance for CO and Propane Oxidation.

Abstract

Most of the industrial and environmental catalytic reactions are operated at high temperature for a long time, and the sintering of the active centers is the main factor leading to catalysts deactivation, especially for noble metal catalysts. Herein we develop a dual confinement (enhanced metal-oxide interaction and the porous shell confinement) strategy to prepare Pd-Sn pseudo solid solution and in situ embedded in microporous silica for the first time and showed superior catalytic performance for CO and propane total oxidation (two main vehicle emission gases), even stored more than 640 days.