In situ Electrochemical Fluorescence Studies of PPV

Abstract

Conjugated phenylene-vinylene polymers are widely used in organic light-emitting and photovoltaic devices. The comprehension of the optical properties upon charge injection is of crucial importance for the improvement of such organoelectronic devices. The processes of electrochemical doping, electrolyte diffusion, and degradation have been studied by cyclic voltammetry and chronoamperometric methods. Kinetic studies by in situ fluorescence spectroscopy have been used for the determination of the mobility of charge carriers in the polymer making used of electrochemical Stern-Volmer analysis. The mobility of holes for MDMO-PPV measured by this method was 2.5 x 10(-7) cm2 V s(-1). Non-Faradic variations of the fluorescence after doping-dedoping cycles have been related to morphological changes in the polymeric layer. The evolution of the fluorescence obeys a first-order kinetics law, similarly to the trend of the variation of volume during gel shrinking.