In-situ detection of electrolyte defects in lithium-ion batteries using ultrasonic imaging and analysis of formation patterns

Abstract

The urgent necessity for enhanced cycling performance in lithium batteries is paramount for electric vehicles to attain broader economic advantages. However, prolonged usage and cycling often lead to electrolyte de-wetting within the battery, posing a significant risk to battery safety and lifespan reduction. A thorough understanding of the mechanisms underlying electrolyte de-wetting is pivotal for the development of long-lasting batteries. This study employs an ultrasonic non-destructive testing method to investigate changes in the internal electrolyte during battery operation. Analysis of the results found that during to the relatively higher current density and temperature near the tabs, electrolyte de-wetting is more prone to occur in these areas, with defects being more severe at the positive electrode compared to the negative electrode. Finally, these issues are addressed to provide reasonable recommendations for future battery design and optimization.