In-situ constructing highly oriented ductile poly(3-hydroxybutyrate-co-3-hydroxyvalerate) nanoribbons: Towards strong, ductile, and good heat-resistant polylactic-based composites

Abstract

It remains a great challenge to manufacture polylactic (PLA) with high strength, ductility, and heat resistance simultaneously. Herein, PLA/poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) nanoribboned composites, the highly oriented PHBV nanoribbons decorated by the PLA lamella, are successfully achieved through the multistage stretching extrusion (MSE) system. SEM confirms that in-situ highly oriented PHBV nanoribbons are achieved by biaxial-stretching field during the MSE process. Through investigating crystalline architecture of PLA/PHBV nanoribboned composites, it is found that the stiff shish and sparse lamellae of PLA are obtained under the coupling effect of PHBV nanoribbons and biaxial-stretching field. DMA reveals partial compatibility between PLA and PHBV. Interestingly, during tensile test, PHBV nanoribbons show high flexibility and synergistically facilitate the stretch of semi-rigid chains of PLA by an effective interfacial interaction. Consequently, even they both are extremely brittle, PLA/PHBV nanoribboned composites exhibit excellent strength (82.9 MPa) and ductility (186.7 %), compared with pure PLA (71.4 MPa and 12.3 %). Additionally, due to the promotion of the crystallization of PLA, PLA/PHBV nanoribboned composites show excellent heat resistance (E′140°C > 350 MPa). The nanoribboned composites are of immense significance, which provide significant guidance for the simultaneous enhancement of ductility and strength of polymer materials.