In situ characterization of Ni-rich NMC811 thin films prepared by sol-gel method using different scanning probe microscopy techniques

Abstract

In this paper, LiNi0.8Co0.1Mn0.1O2 (NMC811) thin films were prepared by the sol-gel method based on different parameter conditions, and the microstructure and electrochemical properties of the films were compared to obtain the film sample under the best preparation parameters. In order to explain the formation mechanism of cell battery performance based on the NMC811 cathode at the nano scale, electrochemical strain microscopy, conductive atomic force microscopy and Kelvin probe force microscopy are specifically utilized to study the changes of NMC811 thin film in electrochemical deformation, conductivity, and potential distribution under different electrical and thermal fields. The results indicate that the local amplitude, conductivity, and electrical potential of thin film in the scanning region increases with the voltage from 0 V to 3 V and the temperature from 25 °C to 150 °C. However, the electrochemical deformation, conductivity, and potential of the film decrease significantly when the voltage is applied to 4 V or the temperature rises to 200 °C.These results provide visual evidence for the influence of external field on the phase structure change and lithium-ion diffusion behavior of NMC811 thin film.