Abstract
Carboxyl, hydroxyl, and other oxygen-containing functional groups play key roles in the interfacial reactions of soil surfaces including biochar (solid-phase slow pyrolysis product) soil amendment. Intensity and directionality in both real (synchronous) and imaginary (asynchronous) coordinates of 2D infrared correlation spectra were confirmed by the time courses of pyrolysis reaction (temperature × wavenumber × absorbance; 10 °C min–1, 1 h residence time at 500 °C) utilizing high-density (74 total spectra) in situ diffuse reflectance Fourier transform (DRIFTs) monitoring. Similar primary trends were observed for four different lignocellulosic biomass feedstocks: cottonseed hull, cotton ginning waste, flax shive, and pecan shell. In the OH stretch region (3100–3750 cm–1), free OH was most sensitive to pyrolysis temperature and reacted before H-bonded OH indicating the evaporation of water, followed by the cleavage of interchain H-bonds. Aromatic CH (R=CHn) was the primary CH functionality (within 2700–3100...
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