In situ anchoring of iron and zinc oxides nanoparticles onto rice husk cellulose for efficient wastewater remediation

Abstract

The development of effective and economical technologies for the treatment of contaminated wastewater has been of great significance to researchers. Therefore, an equal molar ratio of iron and zinc oxides nanoparticles was hydrothermally immobilized on the cellulose fibers of rice husk. Using XRD, SEM, FTIR, EDX, TEM, VSM, BET, and TGA/DTG, the structure, and characteristics of Cel/α-Fe2O3-ZnO, a ternary nanocomposite, were affirmed. The nanocomposite displayed a mesoporous structure with a substantial surface area. The efficiency of nanocomposite as a new adsorbent has been studied for the extraction of reactive black 5 (RB5), which is a diazo-anionic dye from simulated wastewater. The medium's pH was the dominant factor of RB5 adsorption, and the optimal removal effectiveness was acquired at pH 2. The adsorption values of RB5 correspond to second-order kinetics. They also matched Langmuir with a maximum capacity of 99.30 mg g−1. For real industrial wastewater, Cel/α-Fe2O3-ZnO has successfully reduced a number of major pollutants, including ammonia (92.73 %), color (92.88 %), COD (91.53 %), BOD5 (84.97 %), TSS (96.27 %), TP (52.17 %) and TN (47.23 %). These results illustrate the effective application of the ternary nanocomposite in wastewater treatment.