Impulse response function for Brownian motion.

Abstract

Motivated from the central role of the mean-square displacement and its second time-derivative - that is the velocity autocorrelation function in the description of Brownian motion and its implications to microrheology, we revisit the physical meaning of the first time-derivative of the mean-square displacement of Brownian particles. By employing a rheological analogue for Brownian motion, we show that the time-derivative of the mean-square displacement of Brownian microspheres with mass m and radius R immersed in any linear, isotropic viscoelastic material is identical to , where h(t) is the impulse response function (strain history γ(t), due to an impulse stress τ(t) = δ(t - 0)) of a rheological network that is a parallel connection of the linear viscoelastic material with an inerter with distributed inertance . The impulse response function of the viscoelastic material-inerter parallel connection derived in this paper at the stress-strain level of the rheological analogue is essentially the response function of the Brownian particles expressed at the force-displacement level by Nishi et al. after making use of the fluctuation-dissipation theorem. By employing the viscoelastic material-inerter rheological analogue we derive the mean-square displacement and its time-derivatives of Brownian particles immersed in a viscoelastic material described with a Maxwell element connected in parallel with a dashpot and we show that for Brownian motion of microparticles immersed in such fluid-like materials, the impulse response function h(t) maintains a finite constant value in the long term.