Improving UV stability of MAPbI3 perovskite thin films by bromide incorporation

Abstract

Despite the astonishing progress reached in the last five years, perovskite films still lack some stability. It is well known that UV light and humidity affect strongly perovskite-based solar cell performances. We herein investigate the degradation process of perovskite-based CH3NH3PbI3 thin films without encapsulation in presence of direct UV light. The UV irradiation effect on structural, morphological and optical properties of the perovskite thin film is studied. Experimental results show significant degradation of perovskite properties after 12 h of exposure to UV light. The main objective of this work is to show that it is possible to improve the MAPbI3 stability upon UV by the adequate incorporation of the bromide atoms in the perovskite matrix. In fact, it has been found that the CH3NH3Pb(I1-xBrx)3 perovskite exhibits a better stability, distinctly when the bromide fraction is above 20%. We believe that the observed improvement is linked to the structural transition from the tetragonal phase to the more stable cubic structure as shown by the XRD results.