Improving thermal conductivity of styrene ethylene butylene styrene/paraffin/boron nitride phase change composite via the sacrificial template method for battery thermal management

Abstract

To address the bottleneck of easy leakage and low thermal conductivity of phase change materials (PCMs) for battery thermal management. Phase change composite (PCCs) with paraffin (PA) as the PCM, styrene ethylene butylene styrene (SEBS) as the supporting skeleton, and boron nitride (BN) as the thermally conductive filler were fabricated by the sacrificial template method. Compared with the composite prepared by melt-blending method, the thermal conductivity of PCC was improved by 27.6 % and the leakage rate was reduced by 82.4 % because the BN was rubbed with Na2SO4 under the shear provided by internal mixer. As a result, the maximum temperature and maximum temperature difference of the battery pack with PCC cooling were 35.8 % and 62.5 % lower than those without PCC cooling at 2C discharge rate. In total, this work offers a strategy for improving the thermal conductivity and the leakage-proof ability of PCCs as well as for large-scale fabrication.