Improving the water-repellent properties of carbon nanotube-polycarbonate composites by introducing nanoscale patterns into the injection molding process

Abstract

In this study, we explore the impact of hydrophobic nanomaterials, specifically carbon nanotubes (CNTs), on the water repellency of composite materials. These composites are prepared by combining multilayered or single-layered CNTs with polycarbonate (PC). Our goal was to develop highly water-repellent materials by directly forming nanopatterns on the surface through injection molding to enhance water repellency. Irrespective of the CNT type, widening the spacing between surface patterns and increasing the CNT concentration from 0 to 30 wt% resulted in a notable increase in the water contact angle to 161°, surpassing that of Teflon (108°). Moreover, in the multilayered CNT/PC system, a reduction in the sliding angle was observed compared to that of pure polycarbonate, demonstrating a lotus effect-like trend. Conversely, in the case of single-layered CNTs, despite an increase in the contact angle, the sliding angle did not decrease as significantly as in the multilayered CNTs. This implies that the superior transferability during the injection molding process of multilayered CNT/PC compared to single-layered CNT/PC is the underlying factor. This technology holds promise not only in the realm of mobility, such as in the aviation and automotive industries, but also in the medical field, with applications in microfluidic devices.