Improving the Thermal Stability and Flame Retardancy of Epoxy Resins by Lamellar Cobalt Potassium Pyrophosphate.

Abstract

In order to improve the fire retardancy of epoxy resin (EP), lamellar cobalt potassium pyrophosphate (LCPP) nanocrystal whiskers with a length of 100-300 nm were designed and synthesized by a liquid technique. LCPP with high thermal stability was blended into EP to prepare the EP/LCPP composites. The results show that the EP/LCPP composites have higher thermal stability and produce more residues compared to pure EP. The combustion results display that the LOI value of the EP/10wt%LCPP composites was significantly improved to 35.9%, and the EP/6wt%LCPP composite can reach a UL-94 V-1 rating. Additionally, the peak heat release rate and peak smoke production rate of the EP/10wt%LCPP composites dramatically decreased by 43.8% and 48.5%, respectively. The improved flame retardancy and smoke suppression are mainly attributed to the inherent physical barrier of LCPP and the excellent catalytic carbonization ability of LCPP.