Abstract

In the present research, we studied ZnO varistors having multiple dopants and optimized their microstructure and electrical properties by tailoring the sintering process. At certain concentrations of the rare-earth elements yttrium and indium, the voltage gradient decreased from 683.7 to 293.0V/mm as the sintering temperature was increased from 1160 to 1320°C. In addition, the nonlinear coefficient first increased and then decreased as sintering temperature was increased. When sintered at 1240°C, the multiple doped ZnO varistors samples showed excellent performance, exhibiting a voltage gradient of 520V/mm, a residual voltage ratio of 1.55, and a density of 63.7A/cm2 under a current waveform of 8/20μs, and a nonlinear coefficient of 74.5. These optimized properties will be of great utility in the manufacture of metal oxide arresters. When the high-performance varistors were used in surge arresters of ultra-high voltage grids, the overvoltage level along the transmission line and in the substation were reduced by 31.14% and 33.53%, respectively. This combination of characteristics will dramatically improve the protective effect of surge arresters for deeply suppressing over-voltages in power systems, significantly reduce the insulation requirement and cost of power apparatus as well as greatly increase the safety of power systems.

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