Improving the performance of Ca-alginate films through incorporating zein–caseinate nanoparticles-loaded cinnamaldehyde

Abstract

This study aimed to fabricate and characterize the Ca-alginate films functionalized by incorporating zein nanoparticles containing cinnamaldehyde (CA). The zein nanoparticles were coated with Na-caseinate (CN) to inhibit the precipitation of zein in the alginate solution. Afterward, the physical, mechanical, morphological, and barrier properties of the nanocomposite films were evaluated. The particle sizes of different zein nanoparticles (with/without CA and CN) ranged between 43.58 and 251.66 nm. The addition of free CA, zein, and CN nanoparticles significantly increased the thickness, opacity, thermal stability, and water contact angle and improved the mechanical properties of the films. The water vapor permeability was not affected but the antimicrobial activity was improved on fresh-cut apples. The lightness of nanocomposite films decreased and the yellowness and greenness increased. According to SEM and AFM images, a dense and organized interlayer arrangement with a rougher surface was detected in the nanocomposite films. FTIR analysis showed that no new interactions were formed between the Ca-alginate and zein/CN nanoparticles. An excellent sustained CA release into the water was observed for the CA/zein nanoparticles-loaded alginate films. Overall, the results showed that Ca-alginate nanocomposite films of zein nanoparticles have good potential to carry hydrophobic bioactive compounds for specific pharmaceutical and food applications.