IMPROVING THE LONG-TERM DURABILITY OF POLYMERS USED IN BIOMEDICAL APPLICATIONS.

Abstract

Hydrophobic surfaces can improve the long-term mechanical response of polymers by delaying their degradation caused by moisture absorption over time. This improvement in long-term mechanical performance can significantly increase the lifespan of polymers used in various biomedical applications, such as total joint replacement prostheses applications. Although a number of surface modification techniques have been developed over the years, such as introduction of various textures on the surface; their specific influences on hydrophobicity enhancement as well as long-term mechanical performance are yet to be fully understood. In this study, surface textures, with variation in type and geometry, are introduced on model Ultrahigh Molecular Weight Polyethylene (UHMWPE) and High Density Polyethylene (HDPE) surfaces to study the effect of surface modification on hydrophobicity and long-term mechanical performance under environmental conditions. The results show that introduction of surface textures significantly improves the hydrophobicity of model polymers. Texture length or diameter significantly affects the improvement in hydrophobicity. However, texture spacing does not have significant influence on the improvement in hydrophobicity. How this improvement in hydrophobicity facilitates improving the long-term mechanical performance under environmental conditions is investigated. The study provides useful guidelines to improve the long-term mechanical response of polymers for various applications, including biomedical applications.