Abstract

The development of cost-effective, robust, and reliable humidity monitoring system is nowadays in high demand. To this context, humidity sensors based on rutile TiO2 aggregates were prepared via thermal oxidation of pure Ti-discs at 1000°C. The sensors based on only TiO2 aggregates exhibited the ultra-high response of about six orders of magnitude (RA/R%RH∼106) to 90% RH with a response time of 28 s and excellent stability. However, these sensors showed no response to RH below 30%, which limits their use in practical applications for such RH level monitoring. Although with a reduced response in high RH, the TiO2 modified with GO showed potential to overcome this drawback. To understand their functionality, the TiO2 aggregates and TiO2/GO were further characterized by XRD, SEM, TEM, Raman and FT-IR spectroscopy. The presented results are of high interest in terms of wide range humidity monitoring, low-cost and simple synthesis route, and high stability.

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