Abstract

A method is presented that reduces the number of trajectories needed to achieve accurate results with the Herman–Kluk method and similar initial value semiclassical propagation techniques that involve integration over phase space. It is shown that a time average over motion may be inserted into these integrals with the result that their numerical convergence is accelerated. This technique is applied to two systems with encouraging results, especially for long-time propagation.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.