Abstract

Rigorous design of industrial microwave processing systems requires in-depth knowledge of the dielectric properties of the materials to be processed. These values are not easy to measure, particularly when a material is multi-layered containing multiple phases, when one phase has a much higher loss than the other and the application is based on selective heating. This paper demonstrates the ability of the Clausius–Mossotti (CM) model to predict the dielectric constant of multi-layered materials. Furthermore, mixing rules and graphical extrapolation techniques were used to further evidence our conclusions and to estimate the loss factor. The material used for this study was vermiculite, a layered alumina-silicate mineral containing up to 10 % of an interlayer hydrated phase. It was measured at different bulk densities at two distinct microwave frequencies, namely 934 and 2143 MHz. The CM model, based on the ionic polarisability of the bulk material, gives only a prediction of the dielectric constant for experimental data with a deviation of <5 % at microwave frequencies. The complex refractive index model, Landau, Lifshitz and Looyenga, Goldschmidt, Böttcher and Bruggeman–Hanai model equations are then shown to give a strong estimation of both dielectric constant and loss factor of the solid material compared to that of the measured powder with a deviation of <1 %. Results obtained from this work provide a basis for the design of further electromagnetic processing systems for multi-layered materials consisting of both high loss and low loss components.

Highlights

  • The world is under increasing pressure to develop new, more energy efficient technology that enables the production of less waste and is more sustainable [1]

  • The approach was based on testing the validity of the CM theory to estimate the dielectric constant of a multi-layered material by using the properties of constituent phases and the molecular formula of vermiculite

  • This study has established the feasibility of the CM model to connect the dielectric constant of vermiculite to the polarizability of the molecules for such multi-layered materials

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Summary

Introduction

The world is under increasing pressure to develop new, more energy efficient technology that enables the production of less waste and is more sustainable [1]. Material processing through microwave energy has received attention in the past few years for delivering benefits in a number of different applications including; food, fine and bulk chemicals, oil, gas, minerals and metal extraction [2]. Despite the potential to deliver a step change in overall process efficiency across a diverse range of sectors, the benefits of microwave technology are not being realised. The calculation of dielectric properties of multiphase materials by using the dielectric properties and physical characteristics of each of their constituent phases has received considerable attention in the past [4]. Multiphase materials are increasingly used in diverse microwave application areas, but electromagnetic analysis and characterisation efforts are severely lagging behind. The dielectric properties of a material determine how electromagnetic energy will interact with it and are expressed in the form of a complex number (Equation (1)) consisting of a real part (ε’, dielectric constant) and an imaginary part (ε’’, loss factor)

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