Improving the CO and CH4 Gas Sensor Response at Room Temperature of α-Fe2O3(0001) Epitaxial Thin Films Grown on SrTiO3(111) Incorporating Au(111) Islands

Rosalía Cid,Aída Serrano,Jesús López-Sánchez,María Vila,Eduardo Salas-Cólera,Germán R. Castro,Iciar Arnay,Juan Rubio-Zuazo

doi:10.3390/coatings11070848

Abstract

In this work, the functional character of complex α-Fe2O3(0001)/SrTiO3(111) and Au(111) islands/α-Fe2O3(0001)/SrTiO3(111) heterostructures has been proven as gas sensors at room temperature. Epitaxial Au islands and α-Fe2O3 thin film are grown by pulsed laser deposition on SrTiO3(111) substrates. Intrinsic parameters such as the composition, particle size and epitaxial character are investigated for their influence on the gas sensing response. Both Au and α-Fe2O3 layer show an island-type growth with an average particle size of 40 and 62 nm, respectively. The epitaxial and incommensurate growth is evidenced, confirming a rotation of 30° between the in-plane crystallographic axes of α-Fe2O3(0001) structure and those of SrTiO3(111) substrate and between the in-plane crystallographic axes of Au(111) and those of α-Fe2O3(0001) structure. α-Fe2O3 is the only phase of iron oxide identified before and after its functionalization with Au nanoparticles. In addition, its structural characteristics are also preserved after Au deposition, with minor changes at short-range order. Conductance measurements of Au(111)/α-Fe2O3(0001)/SrTiO3(111) system show that the incorporation of epitaxial Au islands on top of the α-Fe2O3(0001) layer induces an enhancement of the gas-sensing activity of around 25% under CO and 35% under CH4 gas exposure, in comparison to a bare α-Fe2O3(0001) layer grown on SrTiO3(111) substrates. In addition, the response of the heterostructures to CO gas exposure is around 5–10% higher than to CH4 gas in each case.

Highlights

CH4 is the main component of natural gas and is widely employed in industrial production [1]
EXAFS parameters are compared with results the α-Fe2 O3 reference that may be related to the greatest local order in the obtained from α-Ferespect epitaxial thin powder films
An island-type growth is recognized in both Au and α-Fe2 O3

Summary

Introduction

CH4 is the main component of natural gas and is widely employed in industrial production [1]. The development of gas sensors capable of monitoring CH4 and CO leakage is essential in the current society to ensure a safer and healthier environment. In this line, metal oxide semiconductors are the most attractive materials for gas sensors since they are chemically stable and can change their resistance when a specific gas interacts with their surface [3,4]. The exploitation of these gas sensors is limited to factors such as the high costs of certain semiconductors and the high temperatures for a good operation [3]

Methods

Results

Conclusion