Improving the Bio-Oil Quality via Effective Pyrolysis/Deoxygenation of Palm Kernel Cake over a Metal (Cu, Ni, or Fe)-Doped Carbon Catalyst.

Abstract

Waste palm kernel cake (WPKC) is being utilized as a biomass feedstock for the sustainable production of catalysts/supports and bio-oil fuels. Herein, metal (Cu, Ni, and/or Fe)-doped carbon catalysts were prepared using conventional impregnation and pyrolysis methods. The physicochemical properties of the as-prepared catalysts were analyzed. According to the obtained results, the catalyst acidity was highly increased with the increase in the metal loading amount on a carbon support, leading to a better performance for deoxygenation/aromatization. A maximum yield of bio-oil from WPKC pyrolysis was achieved up to ∼60% under optimum conditions determined via statistical designs. From the results of bio-oil compositions, 15%Ni loading on activated carbon exhibited the best performance of about 72% for the production of hydrocarbon compounds. Monoaromatic hydrocarbons such as benzene, toluene, and xylenes (BTXs) could be reduced via condensation and polymerization with the increase of the Ni-loading amount. Moreover, the catalytic performance of the selected 15%Ni-carbon catalyst was also compared with those of commercial catalysts zeolite and alumina, and the results showed that the 15% metal-doped carbon catalyst presented much better stability/reusability for five times with less reduction of the hydrocarbon yield in the upgraded bio-oil. This research provided an eco-friendly strategy for the low-cost production of bio-oil fuel with a high quality/yield from waste biomass pyrolysis.