Improving dispersion of basalt fiber with polyethylene glycol and effect of coupling agent

Abstract

ABSTRACT Basalt fibers were widely used as reinforcing matrix materials because of their thermal and chemical stability and environmental friendliness. The properties of composite materials were affected by the interaction between the basalt fibers and matrix materials. Surface modification of basalt fibers and the dispersion property have become key points of research in recent years. This study focuses on the impact of a dispersant on surface modification. Basalt fibers were dispersed by polyethylene glycol (PEG) before modification with 3-aminopropyltriethoxysilane (KH550), which significantly increased the surface roughness, thus increasing the surface area and facilitating mechanical bonding. The morphology, structure, and composition were characterized via scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy analysis (XPS), respectively. The distribution characteristics of fiber were evaluated by the response surface method. When the mass fraction of PEG was 0.5 wt.%, the modification time was 2.5 hours, and the modification temperature was 60°C, the fiber dispersion degree in KH550 solution reached 83%. The grafting degree test indicates that the weight of the grafting increased to 6.67 times that of the undispersed basalt fibers. This enhancement allowed for greater grafting of the KH550, thereby optimizing the effect of modified fibers.