Abstract

Previous recent attempts by the author for giving a more consistent physical meaning to the two-parallel-condenser model and its implications on the adsorption isotherm behaviour are reviewed. In addition, the displacement of oriented water molecules by the adsorbate is taken into account and the effects of a series capacity are discussed. This allows to consider the original expression for the charge density as a function of potential as an approximation of a model much more complex than that first treated. The new expression for the limiting capacity at maximum coverage still allows a consistent analysis from the corresponding experimental parameters.

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