Improvements in gold ore cyanidation by pre-oxidation with hydrogen peroxide

Abstract

It is known that the presence of sulphidic minerals in the cyanidation of gold ores may cause significant consumption of oxygen supplied in the injected air. This may result in dissolved oxygen starvation for the oxidative leaching of the gold, and ultimately it will reduce the maximum attainable recovery of gold from the ore. In addition, the presence of sulphides leads to extra consumption of the cyanide-leaching agent, NaCN, due to the formation of thiocyanate, therefore increasing costs. These types of gold sulphidic ores may be pre-treated prior to cyanidation by means of an oxidation step, converting the sulphides into oxides or sulphates. This treatment leads to a reduction in the consumption of dissolved oxygen and of cyanide in the cyanidation step and to an improvement in the metallurgical recovery. In the current work we present the results of a five month full-scale trial carried out in a gold extraction plant in Brazil, which normally operated with three tanks in series carrying out an alkaline pre-oxidation step using compressed air only, followed by a train of fourteen aerated and mechanically-agitated tanks for the cyanidation. The ore feeding the leaching circuit averages 1.70gAu/t, with about 2.5% of pyrrhotite (FeS) as the main sulphide constituent. The addition of 60L/h of concentrated hydrogen peroxide, H2O2, 50%w/w (density=1.19g/mL) for pre-oxidation of a slurry of 60% solids at a rate of 150t/h (dry ore) resulted in a marked increase in dissolved oxygen (DO). This addition corresponds to a dosing rate of 0.24kg 100%H2O2 per ton of dry ore and increased the dissolved oxygen level from an average of about 1.0 to 7.2mg/L in the pre-oxidation tanks. It also led to an overall reduction of NaCN consumption from an average of 0.52 to 0.40kg/t of ore, and an increase in metallurgical Au recovery from an average of 91.3% to 92.5%.