Improvement of thermal stability of ZrO2–SiO2 aerogels by an inorganic–organic synergetic surface modification

Abstract

The thermal stability of ZrO2–SiO2 aerogels was significantly improved by inorganic–organic synergetic surface modifications: inorganic ions [Fe(III)] surface modification and hexamethyldisilazane gas phase modification. The replacement of Hs from surface hydroxyl groups on the aerogel by Fe(III) ions and silyl groups played a critical role in isolating the hydrous particles of ZrO2–SiO2 aerogels. So the particle growth caused by the condensation of hydroxyl groups upon firing was inhibited. Meanwhile, the decomposition of the silyl groups upon heat treatment produced SiO2 particles, which could serve as pining particle to inhibit the crystallization of ZrO2. Hence, the porous microstructure of the modified aerogels was still well preserved up to 1000 °C, with a high specific surface area of 203.5 m2/g, and a considerable pore volume of 0.721 cc/g. These characteristics of the modified aerogels suggest that it has great potential on ultrahigh-temperature applications in the fields of thermal insulation, catalysis, and catalyst support, etc.