Improvement of the photoluminescent intensity of ZnTa2O6:Pr3+ phosphor

Abstract

A red emitting ZnTa2O6:Pr3+ phosphor with Commission Internationale de l‘Eclairage coordinates that match those of an ideal red emission was prepared by solid state chemical reaction. X-ray diffraction confirmed that a pure orthorhombic phase of ZnTa2O6 was crystallized. A homogeneous distribution of the Pr3+ ions was confirmed from the analysis of the time of flight secondary ion mass spectroscopy overlay images. In addition to the reflectance at 259nm associated with band-to-band absorption, minor reflectance peaks associated with f-f transitions of Pr3+ were observed at 420–500nm. The main red emission peak was split into minor peaks located at 608, 619 and 639nm that were assigned to 1D2⟶3H4, 3P0⟶3H6 and 3P0⟶3F2 transitions of Pr3+, respectively. With increasing concentration of Pr3+, a relatively weak blue emission was observed at 488nm and this phenomenon maybe attributed to virtual charge transfer or/and inter cross relaxation effects. The decay characteristics of the persistent emission were also calculated.