Abstract
The use of a high resistivity transparent oxides (HRT) onto low resistivity transparent oxides (TCO) has been found to improve the performance of CdS/CdTe solar cells. In this work is presented and discussed a study about the use of a commercial conductive glass with SnO2:F as TCO and SnO2 as resistive transparent oxide as front contact in CdS/CdTe solar cells. The SnO2 was deposited by pneumatic spray pyrolysis and its electrical and optical properties were controlled and optimized by varying the substrate temperature and deposition time with the application of a post thermal treatment in O2 atmosphere. The transfer length method (TLM) was implemented to characterize electrically the SnO2:F/SnO2 as well the SnO2/CdS and SnO2:F/SnO2/CdS interfaces through the resistivity and specific contact resistivity measurements and their dependence on O2 treatment were analyzed. The use of the TCO/buffer layer on the CdS/CdTe solar cell in combination with the thermal treatment proposed in this work for TCO and HRT reduced the front contact/CdS contact resistance in a 10 factor and the solar cell efficiency was improved from 6.4% to 12.2%.
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