Improvement of adhesive bonding of grit-blasted steel substrates by using diluted resin as a primer

Abstract

This study reveals the micro-structural details on the metal substrate surface prepared by grit blasting, and then proposes a simple resin pre-coating method aiming at full wetting of the substrate surface for stronger adhesive bonding. The resin pre-coating solution consisting of around 90% acetone and around 10% resin without hardener is used as a primer, which can be sprayed or blushed onto the grit-blasted metal substrate. The acetone solution can carry resin deep into micro-cavities created by grit blasting and effectively coat and wet micro-debris so that micro-voids or gaps between the adhesive joint and metal substrate can be removed. Since the resin pre-coating does not contain hardener and remains wet, the wettability of the substrate is also improved. The normal epoxy adhesive with hardener can then be applied onto the substrate surface. Despite having the primer-like function, the proposed resin pre-coating method still maintains the simplicity of one epoxy resin system. Based on the current study, a resin and acetone solution without hardener does not seem to have adverse effects on the final bonding strengths of adhesive joints, although acetone is known to have detrimental effects on resin and hardener adhesive systems. Four different surface conditions are examined, each having 14 specimens: (1) Grit-Blasted (GB) surface, (2) GB-surface with ultrasonic cleaning, (3) GB-surface with resin Pre-Coating (PC) only, and (4) GB-surface with both ultrasonic cleaning and PC. 25% improvement in the shear strength has been achieved by the resin pre-coating method, even without ultrasonic cleaning, in comparison with 8% improvement after ultrasonic cleaning. These results show GB-surface with PC is beneficial to adhesive bonding, which can be adopted for structural applications even if thorough substrate surface cleaning on site is not possible. The improved wettability of metal substrates after resin pre-coating contributes to the maximum possible utilization of the contact areas over the roughened substrate surfaces and thus leads to the enhanced adhesive bond strength.