Improvement in photocatalytic H2 evolution over g-C3N4 prepared from protonated melamine

Abstract

Porous g-C3N4 (pm-g-C3N4) samples were prepared by sintering protonated melamine. Photocatalytic activities for H2 production over the g-C3N4 samples were evaluated under visible-light irradiation. Specific surface areas and condensation degree of the g-C3N4 samples prepared from protonated melamine turn larger as the calcination temperatures increase (400°C, 450°C, 500°C, 550°C, and 580°C for 1h). Also, their bandgaps are narrowed and PL peak red shifts, and thus their photocatalytic activities are enhanced. Compared with the reference g-C3N4 samples synthesized by sintering melamine without any protonation (m-g-C3N4), the pm-g-C3N4 samples exhibit better photocatalytic performances, owing to larger specific surface area, less recombination of photogenerated carriers and higher degree of condensation. By optimizing the preparation parameters and the amount of Pt cocatalyst, the highest hydrogen evolution rate of 417μmolh−1g−1 was achieved over the pm-g-C3N4 samples synthesized at 550°C for 2h, when irradiated by 300-W Xe lamp with a cutoff filter (λ≥420nm).