Improved yield parameters in catalytic steam gasification of forestry residue; optimizing biomass feed rate and catalyst type

Abstract

The catalytic gasification (900 °C) of forestry industry residue ( Eucalyptus saligna) was laboratory-studied. Biomass feed rate and type and amount of catalyst were assayed for their effect on the gasified product composition and the overall energy yield of the gasification reaction. The use of a calcined dolomite catalyst resulted in a combustible gas mixture of adequate calorific power (10.65 MJ m −3) for use as fuel, but neither the product gas composition nor the energy yield varied significantly with widely different amounts of the catalyst (2 g and 20 g). The use of NiO-loaded calcined dolomite catalysts did not affect the product gas composition significantly but led to a 30% increase in the total product gas volume and to a reduction in the rate of tar and char formation. The catalyst loaded with the smallest amount of NiO studied (0.4 wt%. Ni/Dol) led to the highest energy yield (21.50 MJ kg −1 on a dry-wood basis) based on the use of the gasified product as fuel. The gasified product was found to have an adequate H 2/CO molar ratio and H 2 content for use as synthesis gas source and partial source of H 2.