Improved two-step anodization technique for ordered porous anodic aluminum membranes

Abstract

We report on an improved two-step anodization technique through combining the first hard anodization in C 2H 2O 4 with the second mild anodization in H 3PO 4, which successfully overcome the drawbacks of irregular top surfaces in the conventional two-step hard anodization in C 2H 2O 4 and disordered pore arrays in the two-step mild anodization in H 3PO 4. The key success of our method is the strong guidance effect of the first hard anodization on the second mild anodization. Highly-ordered (both top and bottom surfaces) porous anodic aluminum (PAA) membranes with interpore spacing from 220 to 350 nm have been realized under anodizing voltages from 100 to 150 V. The interpore spacing is only determined by the first anodizing voltage, while the pore diameter can be manipulated in the second step by adding ethanol in the H 3PO 4 electrolyte, changing the H 3PO 4 bath temperature, and altering the second anodizing voltage. The bath temperature for the steady growth of ordered structures can be expanded up to 20 °C, from which the average activation energy can be yielded. The present novel two-step anodization approach is simple, efficient, and cost-effective. It expands the self-ordering regime of PAA membranes, which is of great value for applications in diverse areas of nanotechnology.