Abstract

Bio-degradable and eco-friendly plasticized starch/reduced graphene oxide (PS/rGO) nanocomposites were made by a simple aqueous casting method. The effect of the rGO nanofiller on the structural, surface-morphological, mechanical, thermal, and electrochemical properties of the nanocomposite was studied. rGO enhances the thermal stability and significantly improves the mechanical strength of the polymer nanocomposite. The PS/rGO nanocomposite exhibits improved electrochemical performance and a specific capacitance as high as 42.25 F/g at a current density of 0.1 mA/cm2, which is about 20 times higher than that of PS (2.51 F/g). These improved thermal, mechanical, and electrochemical properties of the PS/rGO may be attributed to the good interfacial interaction and preferential orientation of rGO sheets in the nanocomposites. The PS/rGO nanocomposites with improved thermal and mechanical properties together with enhanced electrochemical performance produced from an easy and low-cost process will provide a sustainable way for the fabrication of eco-friendly energy storage devices.

Highlights

  • With the fast progress of electronic devices in this era, some unique substances with significant dielectric constant have garnered prominent research interest among scientists and researchers.1,2 With the potential to be used in several fields, such as high energy density capacitors,1 random access memory,3 and different conversion applications,4 nanomaterials with potent dielectric properties have proclaimed eloquent regard

  • The effect of Reduced graphene oxide (rGO) on the structural, mechanical, and thermal properties of plasticized starch (PS) was reported in several articles;20,25,34 the influence of rGO loading on the electrochemical performance of the PS matrix was never evaluated

  • In this article, we report the synthesis of plasticized starch/reduced graphene oxide (PS/rGO) composites through a facile solution cast method

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Summary

INTRODUCTION

With the fast progress of electronic devices in this era, some unique substances with significant dielectric constant have garnered prominent research interest among scientists and researchers. With the potential to be used in several fields, such as high energy density capacitors, random access memory, and different conversion applications, nanomaterials with potent dielectric properties have proclaimed eloquent regard. With the potential to be used in several fields, such as high energy density capacitors, random access memory, and different conversion applications, nanomaterials with potent dielectric properties have proclaimed eloquent regard. Their prime mechanical properties, outstanding flexibility together with the notable facility of fabrication, have acclaimed them to be a dominating contender as a fundamental component for future procreation of pliable electronic devices.. The effect of rGO on the structural, mechanical, and thermal properties of PS was reported in several articles; the influence of rGO loading on the electrochemical performance of the PS matrix was never evaluated. The specific capacitances of PS were found to be improved from 2.51 and 42.25 F/g for the PS/rGO nanocomposite

Materials
Preparation of reduced graphene oxide
Synthesis of potato starch
Characterization of nanocomposites
RESULTS AND DISCUSSION
Surface morphology analysis
Thermal properties
Mechanical properties
Electrochemical properties
CONCLUSIONS

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