Abstract
A technique for the polarographic determination of stability constants, including preparation of solutions within the polarographic cell and use of a three-electrode system for measurement, is presented. The necessity for numerical treatment of polarographic data and the use of a digital computer are discussed. A block diagram for complete numerical least-squares treatment of data is given. E1/2 and id are obtained by simultaneous refinement of graphically estimated values, while the stability constants are obtained by least-squares fitting of the weighted Leden polynomial, F0, to experimental data. The technique has been applied to the system of lead 2-hydroxybutyrato complexes.
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