Abstract
Inulin, a polydisperse reserve polysaccharide extracted from chicory, has been modified by alkoxylation in a water-free medium using a basic catalyst. The reaction of inulin with ethylene oxide, as well as propylene oxide, was performed in an organic solvent, N-methylpyrrolidinone, with triethylamine as basic catalyst in almost quantitative yields. The reaction resulted in a range of products with very specific properties such as highly increased water solubility, moderate surface activities and very high cloud points in electrolyte media.
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