Abstract

In the present paper we derive the new generalized energy sudden approximattion theory and the generalized adiabatic nuclei theory of atom-diatomic molecule scattering through the transformation of the full Green operator. The derivation is quite simple and it is different from previous methods. The formulation has an obvious physical meaning and should lead to accurate numerical results. Numerical results for H e-H 2 scattering are given and compared with previous results.

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