Improved separation efficiency of polyamide-based composite nanofiltration membrane by surface modification using 3-aminopropyltriethoxysilane

Abstract

• Separation efficiency of PA NF membrane was improved by modification with APTES. • Modification was fulfilled via surface cross-linking and in-situ condensation. • Homogenized pore size and reduced mean pore diameter were achieved by modification. • Removal efficiency to both cationic and anionic dye aqueous solutions was improved. • Anti-fouling resistances to model foulants CTAB, HA and BSA were enhanced. Surface modification has been adopted to tune surface property of nanofiltration membrane for improved separation performance. However, it has rarely been explored to modulate membrane pore size distribution. Here, we reported a novel modification strategy combined with surface cross-linking and in-situ condensation for fabricating composite nanofiltration membrane with reduced and homogenized pore size. The strategy was fulfilled by soaking the surface of nascent polyamide-based membrane with an aqueous solution of 3-aminopropyltriethoxysilane (APTES). Membrane physico-chemical property analyses demonstrated that the hydrolyzed APTES molecules bonded onto membrane surface through amidation and esterification reactions with the residual acyl chloride groups, and chemically combined with each other through condensation reaction. Modification was found to hydrophilize membrane surface, homogenize pore size and reduce mean pore diameter. The modification under desired conditions led to an improvement in pure water permeance from 12.2 to 14.0 l/m 2 h bar, a decrease in geometric mean pore diameter from 0.71 nm to 0.63 nm, and a decline in geometric standard deviation from 1.32 to 1.23. Permeation test results showed that the APTES-modified membrane also exhibited improved removal performance to methylene blue and cresol red removal and enhanced antifouling resistances to model foulants cetyltrimethylammonium bromide, humic acid and bovine serum albumin.