Improved performance of Bis-GMA/TEGDMA dental composites by net-like structures formed from SiO2 nanofiber fillers

Abstract

The major objective of this study was to explore the effects of silicon dioxide (SiO2) nanofibers on the performance of 2, 2-bis-[4-(methacryloxypropoxy)-phenyl]-propane (Bis-GMA)/tri-(ethyleneglycol) dimethacrylate (TEGDMA) dental composites. At first, the mechanical properties of Bis-GMA/TEGDMA (50/50, w/w) resins containing different contents of SiO2 nanofibers were evaluated to identify the appropriate composition to achieve the significant reinforcing effect. Secondly, optimized contents (5 or 10wt.%) of SiO2 nanofibers were mixed into resins together with SiO2 microparticles, which was 60wt.% of the resin. Controls for comparison were Bis-GMA/TEGDMA resins containing only SiO2 microparticles (60wt.%) or with additional SiO2 nanoparticles (5 or 10wt.%). Properties including abrasion, polymerization shrinkage and mechanical properties were evaluated to determine the contribution of SiO2 nanofibers. In comparison with SiO2 nanoparticles, SiO2 nanofibers improved the overall performance of Bis-GMA/TEGDMA composite resins, especially in improving abrasion resistance and decreasing polymerization shrinkage. The explanations were that one-dimensional SiO2 nanofibers were able to shield particular fillers from being abraded off, and able to form a kind of overlapped fibrous network to resist polymerization shrinkage. With these approaches, SiO2 nanofiber-containing Bis-GMA composite resins were envisioned a promising choice to achieve long-term durable restorations in clinical therapies.