Improved n-ZnO nanorods/p-Si heterojunction solar cells with graphene incorporation

Abstract

The present research explored the effect of graphene layer and zinc oxide nanorods (NRs) on the photovoltaic performance of ZnO thin film-based heterojunction solar cells. For this purpose, ZnO thin film was deposited on p-type silicon using radio frequency sputtering to serve as an anti-reflective layer and n-type semiconductor to form a heterojunction thin film solar cell. Then, a cost-effective and facile chemical bath deposition technique was employed to synthesize ZnO NRs. To study the effect of reduced graphene oxide (rGO) on the optical properties of ZnO NRs, the colloidal suspension of rGO and ZnO NRs (rGO:ZnO NRs) was prepared. The optimized nanostructures were then transferred to the surface of the ZnO/Si sample using a drop-cast method. The morphological examination of the nanostructures showed the formation of ZnO NRs with various orientations which can significantly increase the entrapment of incident photons. The XRD results indicated an improvement in the structural properties of ZnO NRs upon adding rGO flakes. The reduction of GO was confirmed using Raman spectroscopy. The higher ID/IG ratio for the rGO:ZnO NRs sample (compared to GO layers) suggested the chemical reduction of GO. The optical investigations revealed an increment in the light absorption and PL intensity in the rGO-containing samples which can be due to the role of graphene as a reinforcement phase to inhibit the electron-hole recombination. The optoelectrical properties of fabricated solar cells were investigated via the metallization of top and rear contacts to fabricate three different solar cells based on ZnO thin film, ZnO NRs, and rGO:ZnO NRs. The results showed an enhancement in the efficiency (14.12%) and the fill factor (0.552) of the solar cell based on rGO:ZnO NRs compared to the other solar cells. Therefore, the incorporation of rGO can improve the photovoltaic properties of solar cells based on ZnO nanorods.