Abstract
Abstract A vibration-rotation band system of acetylene of the /Πu bending vibration v5 has been recorded with high resolution by a Bruker IFS 120 HR Michelson spectrometer. From the analysis of the hot band of the normal isotopic species, v4 + v5 - v4, and the fundamental band of HC13CH in natural abundance an improved set of constants has been derived. The intensity perturbation due to the l-type resonance has been clearly observed in the band system v4 + v5 -v4
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