Improved microstructure and mechanical properties by in-situ formed nano borides of high-Nb TiAl composites under ultrasound in the solid-liquid two-phase region

Abstract

To form in situ nano-borides in the solid-liquid two-phase region, Ti46 A l8Nb2·6C0.8TaxB alloys were prepared under ultrasound to improve the microstructural and mechanical properties. The morphology and distribution of borides and the characteristics of lamellar colonies were observed with scanning and transmission electron microscopy and X-ray diffraction; these analyses revealed the influence of borides on microstructural evolution and improved strength and plasticity. The borides that form are elongated and spherical. As the B content increases, the borides gradually spheroidise, and nano-borides precipitate on the lamellar phase. There are a large number of dislocations around the borides to form stacking faults and dislocation walls. The average size of the lamellar colonies decreases from 26.9 to 19.3 μm. The increase in boride nucleation sites as the B content increases and ultrasound-mediate breaking of primary borides are the reasons for forming B27-type borides. The increase in nucleation particles refines the lamellar colony. The compressive strength increases from 2058 to 2299 MPa, and the strain increases from 25.2% to 32.3% when the addition of B increases from 0% to 1.2%. The significantly improved mechanical properties are due to uniformly distributed nano-borides that hinder the movement of dislocations to form stacking faults and dislocation walls and refinement of the lamellar colonies.