Abstract

SnO2/Zn2SnO4 hollow microspheres with porous shell (HPMSs) were successfully prepared by using ZnSn(OH)6 (ZHS) hollow microspheres (HMSs) as sacrificial templates, which were pre-synthesized via a fast solid-state grinding method combined with subsequent chemical etching process. The obtained samples were characterized by XRD, SEM, TEM, and N2 adsorption-desorption, respectively. Results indicated that the diameter of the prepared SnO2/Zn2SnO4 HPMSs were around 300–700nm and their shell-thickness was about 50nm. On the shell of the composite HPMSs, a large number of 5–20nm pores were in situ created. In comparison with the SnO2/Zn2SnO4 porous microspheres (PMSs) that prepared directly from solid ZHS microspheres, the SnO2/Zn2SnO4 HPMSs exhibited much higher sensitivity to formaldehyde, demonstrating the improved gas-sensing performance through structural evolution from PMS to HPMS.

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