Improved densification and mechanical properties of spark plasma sintered carbon nanotube reinforced alumina ceramics

Abstract

Dense magnesium oxide (MgO) doped multiwalled carbon nanotube (MWCNT) reinforced alumina (Al2O3) nanocomposites were fabricated using spark plasma sintering (SPS). Sintered nanocomposites possessed refined microstructure due to the presence of uniformly dispersed CNTs and ability of MgO to increase densification rate before onset of abnormal grain growth. Williamson-Hall analyses of XRD patterns indicated that matrix crystallite size (LC) and lattice micro-strain (εC) of the nanocomposites decreased by ∼40% and >30%, respectively, than those of pure Al2O3 (LC ≈ 75 nm, εC = 1.54 × 10−3). Present investigation also depicted the suitability of CNT addition in Al2O3 towards achieving higher density of nanocomposites using low temperature (1300 °C) SPS. Addition of CNT (especially, at ≥0.6 vol.%) in highly electrically insulating matrix established an electrical percolating network that helped in local heating of matrix particles during SPS and led to higher densification. The highest changes in indentation fracture toughness at 1 kgf and wear rate at 20N normal load were obtained at only 0.6 vol.% MWCNT loading which were >22% higher and 35% lower, respectively, compared to pure Al2O3.