Improved color purity and efficiency by a coguest emitter system in doped red light-emitting devices

Abstract

We demonstrate red organic light-emitting diodes (OLEDs) with improved color purity and electroluminescence (EL) efficiency by codoping a green fluorescent sensitizer 10-(2-benzothiazolyl)-2,3,6,7-tetrahydro-1,1,7,7-tetramethyl-1 H,5 H,11H-(1)-benzopyropyrano(6,7-8-i,j)quinolizin-11-one (C545 T) as the second dopant and a red fluorescent dye 4-(dicyanomethylene)-2-t-butyl-6(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran (DCJTB) as the lumophore into tris(8-hydroquinoline) aluminum (Alq 3) host. It was found that the C545 T dopant did not by itself emit but assisted the carrier trapping from the host Alq 3 to the red emitting dopant. The red OLEDs realized by this approach not only kept the purity of the emission color, but also significantly improved the EL efficiency. The current efficiency and power efficiency, respectively, reached 12 cd/A at a current density of 0.3 mA/cm 2 and 10 lm/W at a current density of 0.02 mA/cm 2, which are enhanced by 1.4 and 2.6 times compared with devices where the emissive layer is composed of the DCJTB doped Alq 3, and a stable red emission (chromaticity coordinates: x = 0.64 , y = 0.36 ) was obtained in a wide range of voltage. Our results indicate that the coguest system is a promising method for obtaining high-efficiency red OLEDs.