Abstract

Polyester (PET) fibers must undergo impregnation with a resorcinol-formaldehyde-latex (RFL) solution to ensure efficient adhesion with rubber. However, the harmful, carcinogenic resorcinol-formaldehyde (RF) resin in RFL impregnation solution negatively affects human health. In this paper, PET was pretreated with blocked isocyanate and epoxy resins to activate the fibers, and a new environmentally friendly fiber impregnation coating was developed. In the new impregnation coatings, ethylene glycol diglycidyl ether (EGDE) and m-xylylenediamine (MXDA) were applied to replace the resorcinol and formaldehyde. Moreover, glycidyl methacrylate (GMA) containing epoxy groups and double bonds was introduced to enhance interaction with rubber further, and then styrene-butadiene-vinyl-pyridine (VP) latex was mixed. The results show that the peel strength of the impregnated PET/rubber composites with the new impregnation coatings can reach 14.0 N/mm, representing an increase of 30.8 % compared to that of the sample with the pure RFL impregnation coatings, whose peel strength is only 10.7 N/mm. Furthermore, the mechanism for enhancing the interfacial adhesive properties of PET/rubber composites was performed by analyzing the chemical composition and morphological changes of the impregnated PET surface, as well as the change of sulfur content at the interface of the impregnated PET/rubber composites and the transition gradient of interfacial modulus.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call