Impregnation and mechanical properties of three softwoods treated with a new fire retardant chemical

Abstract

Three softwoods, Sugi (Cryptomeria japonica), Korean Pine (Pinus koraiensis) and Hinoki (Chamaecyparis obtusa), were vacuum–pressure impregnated with a fire retardant chemical consisting of ammonium phosphate polymer (APP), guanyl urea phosphate (GUP), phosphonic acid and a minor amount of additives. The variation in impregnation between and within wood species was investigated. A significant relationship and similar trends were found between fire retardant chemical (FR) uptake and specific gravity (SG), as well as void volume filled (VVF) and SG. Moreover, the effects of fire retardant treatment on mechanical properties, including modulus of rupture (MOR), static modulus of elasticity (MOE) and dynamic modulus of elasticity (DMOE), were evaluated. The results indicated that the trend of impregnation and regression function varied between species and positions within the same species. However, the relationship of SG and chemical uptake and that of VVF and chemical uptake could be represented by a positive linear regression, and the trends were similar between wood species. Both of SG and VVF increased with increasing FR uptake. After fire retardant treatment, the MOR and static MOE were reduced compared with before treatment. Conversely, the DMOE increased after treatment.