Abstract
Sorption of four perfluoroalkyl carboxylic acids (PFCAs) including perfluoropentanoic acid, perfluoroheptanoic acid, perfluorodecanoic acid, and perfluorododecanoic acid by three soils with cation exchange sites occupied by K+, Ca2+, or Fe3+ was measured using the batch equilibration method. We hypothesize that partitioning in soil organic matters (SOM) is the primarily operative mechanism for PFCA sorption by K+-soils, and sorption by Ca2+- or Fe3+-soils could be enhanced via cation-bridging interaction. The measured sorption isotherms for all four PFCAs by soils were linear within the aqueous concentration between 0 and 60 μg/L, and the distribution coefficients ranged between 14.8 and 173 L/kg. Long-chain PFCAs manifested greater sorption by the soils with higher SOM content. Compared to sorption by K+-soils, sorption of PFCAs by Ca2+- and Fe3+-soils increased by 19.9–90.2% and 38.5–219%, respectively. The relative contributions of cation-bridging interaction to the overall PFCA sorption were estimated to be 16.6–48.7% for Ca2+-soils and 27.8–67.7% for Fe3+-soils. These results demonstrate that multivalent exchangeable cations could play an important role, yet previously ignored, in controlling sorption and transport of PFCAs in soils.
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