Implementation of synaptic learning rules by TaO x memristors embedded with silver nanoparticles* *Project supported by the National Natural Science Foundation of China (Grant No. 61674038), the Natural Science Foundation of Fujian Province, China (Grant No. 2019J01218), the Fund from the Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China (Grant No. 2021ZR145), and the Science Fund from

Abstract

As an alternative device for neuromorphic computing to conquer von Neumann bottleneck, the memristor serving as an artificial synapse has attracted much attention. The TaO x memristors embedded with silver nanoparticles (Ag NPs) have been fabricated to implement synaptic plasticity and to investigate the effects of Ag NPs. The TaO x memristors with and without Ag NPs are capable of simulating synaptic plasticity (PTP, STDP, and STP to LTP), learning, and memory behaviors. The conduction of the high resistance state (HRS) is driven by Schottky-emission mechanism. The embedment of Ag NPs causes the low resistance state (LRS) conduction governed by a Poole–Frenkel emission mechanism instead of a space-charge-limited conduction (SCLC) in a pure TaO x system, which is ascribed to the Ag NPs enhancing electric field to produce additional traps and to reduce Coulomb potential energy of bound electrons to assist electron transport. Consequently, the enhanced electric fields induced by Ag NPs increase the learning strength and learning speed of the synapses. Additionally, they also improve synaptic sensitivity to stimuli. The linearity of conductance modulation and the reproducibility of conductance are improved as well.